publications
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71. Impact of Surface Enhanced Raman Spectroscopy in Catalysis
Stefancu, A., Aizpurua, J., Alessandri, I., Bald, I., Baumberg, J., Besteiro, L., Christopher, P., Correa-Duarte, M., de Nijs, B., Demetriadou, A., Frontiera, R. R., Fukushima, T., Halas, N., Jain, P., Kim, Z. H., Kurouski, D., Lange, H., Li, J.-F., Liz-Marzán, L., Lucas, I. T., Meixner, A., Murakoshi, K., Nordlander, P., Peveler, W., Quesada-Cabrera, R., Ringe, E., Schatz, G., Schlücker, S., Schultz, Z., Tan, E. X., Tian, Z-Q., Wang, L., Weckhuysen, B., Xie, W., Ling, X. Y., Zhang, J., Zhao, Z., Zhou, R.-Y., Cortés, E., ACS Nano, 2024
70. Resonance Raman Intensity Analysis of Photoactive Metal-Organic Frameworks
Brennan, J., Choi, T. H., Soilis, Z., Rosi, N., Johnson, J. K., Frontiera, R. R., The Journal of Chemical Physics, 2024
69. Killer Phonon Caught: Femtosecond Stimulated Raman Spectroscopy Identifies Phonon-Induced Control of Photochemistry in Rubrene Derivatives
Clapham, M. L.+, Das, A.+, Douglas, C., Frontiera, R. R., Journal of the American Chemical Society, 2024
68. Evidence for Superoxide-Initiated Oxidation of Aniline in Water by Pulsed, Atmospheric Pressure Plasma
Clay, D., Mueller, C. M., Rich, C. C., Schatz, G. C., Bruggeman, P. J., Frontiera, R. R., The Journal of Physical Chemistry Letters, 2024
67. Wavelength Dependence of Plasmon-Induced Vibrational Energy Transfer in Fluorophore−Plasmonic Systems
Christenson, G. N., Yu, Z., Frontiera, R. R., The Journal of Physical Chemistry C, 2024
66. Probing Time-Resolved Plasma-Driven Solution Electrochemistry in a Falling Liquid Film Plasma Reactor: Identification of HO2- as a Plasma-Derived Reducing Agent
Srivastava, T., Chaudhura, S., Rich, C. C., Schatz., Frontiera, R. R., Bruggeman, P. , The Journal of Chemical Physics, 2024
65. Cinchona Alkaloid Polymers Demonstrate Highly Efficient Gene Delivery Dependent on Stereochemistry, Methoxy Substitution, and Length
Kreofsky, N. W, Roy, P., Brown, M. E., Perez, U., Leighton, R. E., Frontiera, R. R., Reineke, T. M., Biomacromolecules, 2024
64. Structural Disorder at the Edges of Rubrene Crystals Enhances Singlet Fission
Volek, T. S., Armstrong, Z. T., Sowa, J. K., Wilson, K. S., Kunz, M. B., Bera, K., Koble, M., Frontiera, R. R., Rossky, P. J., Zanni, M. T., Roberts, S. T., The Journal of Physical Chemistry Letters, 2023
63. Quantifying the ultrafast and steady-state molecular reduction potential of a plasmonic photocatalyst
Warkentin, C. L., Frontiera, R. R., Proceedings of the National Academy of Sciences, 2023
62. Mastering Femtosecond Stimulated Raman Spectroscopy: A Practical Guide
Lynch, P. G., Das, S., Alam, S., Rich, C. C., Frontiera, R. R. The Journal of Physical Chemistry Au, 2023
61. Quantifying Bacteriorhodopsin Activity as a Function of its Local Environment with a Raman-Based Assay
Leighton, R. E., Frontiera, R. R., Journal of Physical Chemistry B 2023
60. Ligand Chromophore Modification Approach for Predictive Incremental Tuning of Metal−Organic Framework Color
Soilis, Z. M., Choi, T. H., Brennan, J., Frontiera, R. R., Johnson, J. K., Rosi, N. L., Chemistry of Materials, 2023
59. Mixed Rubrene Cocrystals Offer Insights into Intermolecular Interactions Influencing Crystal Packing
Clapham, M., Frontiera, R. R., Douglas, C. Crystal Growth and Design, 2023
https://pubs.acs.org/doi/10.1021/acs.cgd.3c00296
58. Ostensible Steady-State Molecular Cooling with Plasmonic Nanoparticles
57. Stimulated Raman versus Inverse Raman: Investigating Depletion Mechanisms for Super-Resolution Raman Microscopy
Leighton, R. E., Alperstein, A. M., Punihaole, D., Silva, W. R., Frontiera, R. R. The Journal of Physical Chemistry B, 2022
https://pubs.acs.org/doi/10.1021/acs.jpcb.2c04415
56. Virtual Special Issue on Quantum Coherent Phenomena in Energy Harvesting and Storage
Frontiera, R. R. The Journal of Physical Chemistry B and C, 2022
https://doi.org/10.1021/acs.jpcb.2c04774
55. Synergies between Polyacrylamide Polymerization and Nanoparticle Generation using an Atmospheric Pressure Plasma Jet
Gangal, U., Exarhos, S., Contreras, T., Rich, C. C., Dolan, K., Yang, V., Frontiera, R. R., Bruggeman, P. Plasma Processes and Polymers, 2022
54. Label-free super-resolution imaging techniques
Leighton, R., Alperstein, A., Frontiera, R. R. Annual Review of Analytical Chemistry, 2022
https://www.annualreviews.org/doi/abs/10.1146/annurev-anchem-061020-014723
53. Intermolecular forces dictate vibrational energy transfer in plasmonic-molecule systems
52. Beyond single crystals: Imaging rubrene polymorphism across crystalline batches through lattice phonon Raman microscopy
Clapham, M. L, Leighton, R. E., Douglas, C. J., Frontiera, R. R. The Journal of Chemical Physics, 2021
https://doi.org/10.1063/5.0065496
51. Femtosecond stimulated Raman spectroscopy – guided screening leads to efficient singlet fission in rubrene derivatives
Bera, K., Douglas, C. D., Frontiera, R. R. Chemical Science, 2021
https://doi.org/10.1039/D1SC04251C
50. Vibronic Coupling and Exciton Chirality: Electronic and Structural Rearrangement between Helical to Zero Momentum Molecular Exciton States
Rich, C. C., Frontiera, R. R. The Journal of Physical Chemistry C, 2021
https://dx.doi.org/10.1021/acs.jpcc.1c05827
49. Decoding Chemical and Physical Processes Driving Plasmonic Photocatalysis Using Surface-Enhanced Raman Spectroscopies
Warkentin, C. L., Yu, Z., Sarkar, A., Frontiera, R. R. Accounts of Chemical Research, 2021
https://doi.org/10.1021/acs.accounts.1c00088
48. Plasma-Driven Solution Electrolysis
Bruggeman, P., Frontiera, R. R., Kortshagen, U., Kushner, M., Linic, S., Schatz, G. C., Andaraarachchi, H., Exarhos, S., Jones, L., Mueller, C., Rich, C. C., Xu, C., Yue, Yuanfu, Zhang, Yi. Journal of Applied Physics, 2021
https://doi.org/10.1063/5.0044261
47. Quinine copolymer reporters promote efficient intracellular delivery and illuminate protein-induced DNA unpackaging mechanisms
Van Bruggen, C., Punihaole, D., Keith, A. R., Schmitz, A. J., Tolar, J., Frontiera, R. R., Reineke, T. M. Proceedings of the National Academy of Science USA, 2020
https://doi.org/10.1073/pnas.2016860117
46. Plasmon-mediated intramolecular methyl migration with nanoscale spatial control
Brooks, J. L., Chulhai, D. V., Goodpaster, J. D., Frontiera, R. R. ACS Nano, 2020
https://doi.org/10.1021/acsnano.0c07123
45. Advancements in singlet fission chromophore design enabled by vibrational spectroscopies
Bera, K.*, Kwang, S. Y.*, Frontiera, R. R., The Journal of Physical Chemistry C, 2020
https://doi.org/10.1021/acs.jpcc.0c06725
44. Coherent phonon catalysts: Lattice vibrations drive a photoinduced phase transition in a molecular crystal
Rich, C., Frontiera, R. R. The Journal of Physical Chemistry Letters, 2020
http://dx.doi.org/10.1021/acs.jpclett.0c01834
43. Stimulated Raman imaging below the diffraction limit with a MHz laser
Graefe, C. T., Punihaole, D., Lynch, M. J., Silva, W. R., Frontiera, R. R. The Journal of Raman Spectroscopy, 2020
https://doi.org/10.1002/jrs.5970
42. Femtosecond stimulated Raman spectro-microscopy for probing chemical reaction dynamics in solid-state materials
Cassabaum, A. A., Bera, K., Rich, C. C., Nebgen, B. R., Kwang, S. Y., Clapham, M. L., Frontiera, R. R. The Journal of Chemical Physics, 2020
41. Spatially Offset Femtosecond Stimulated Raman Spectroscopy: Observing Exciton Transport through a Vibrational Lens
Kwang, S. Y., Frontiera, R. R. The Journal of Physical Chemistry Letters, 2020
https://doi.org/10.1021/acs.jpclett.0c01114
40. Plasmon-driven C-N bond cleavage across a series of viologen derivatives
Brooks, J. L., Chulhai, D. V., Yu, Z., Goodpaster, J. D., Frontiera, R. R. The Journal of Physical Chemistry C, 2019
39. Probing the coupling of butterfly wing photonic crystals to plasmon resonances with surface-enhanced Raman spectroscopy
Palmer, L. D., Brooks, J. L., Frontiera, R. R. The Journal of Materials Chemistry, 2019
38. Effective Background Removal in Femtosecond Stimulated Raman Spectroscopy Using a Dual Frequency Raman Pump Technique
Bera, K., Kwang, S. Y., Cassabaum, A. A., Rich, C. C., Frontiera, R. R. The Journal of Physical Chemistry A, 2019
37. Far-Field Super-Resolution Vibrational Spectroscopy
Graefe, C. T., Punihaole, D., Harris, C. M., Lynch, M. J., Leighton, R., Frontiera, R. R. Analytical Chemistry, 2019
36. Orientation and Polarization Dependence of Ground and Excited-State FSRS in Crystalline Betaine-30
Cassabaum, A. A., Silva, W. R., Rich, C. C., Frontiera, R. R. The Journal of Physical Chemistry C, 2019
35. Plasmon-Enhanced Chemical Sensing and Conversion using Copper Selenide Nanoparticles
Gan, X. Y., Keller, E. L., Warkentin, C. L., Crawford, S., Frontiera, R. R.,* Millstone, J. E.* Nano Letters, 2019
34. Carborane RAFT Agents as Tunable and Functional Molecular Probes for Polymer Materials
Messina, M., Graefe, C. T., Chong, P., Ebrahim, O. M., Pathuri, R. S., Bernier, N. A., Mills, H. A., Rheingold, A. L., Frontiera, R. R., Maynard, H. D., Spokoyny, A. M. Polymer Chemistry, 2019
33. Effect of Silica Supports on Plasmonic Heating of Molecular Adsorbates as Measured by Ultrafast Surface-Enhanced Raman Thermometry
Keller, E. L., Kang, H., Haynes, C. L., Frontiera, R. R. ACS Applied Materials and Interfaces, 2018
32. New insights into quinine-DNA binding using Raman spectroscopy and molecular dynamics simulations
Punihaole, D., Workman, R. J., Upadhay, S., Van Bruggen, C., Schmitz, A., Reineke, T. M., Frontiera, R. R. The Journal of Physical Chemistry B, 2018
31. Toward a mechanistic understanding of plasmon-mediated photocatalysis
Brooks, J. L., Warkentin, C. L., Saha, D., Frontiera, R. R. Nanophotonics, 2018
30. Ultrafast nanoscale thermometry proves heating is not a significant factor in plasmonic photocatalysis
Keller, E. L., Frontiera, R. R. ACS Nano, 2018
29. Femtosecond stimulated Raman evidence for charge-transfer character in pentacene singlet fission
Hart, S. M., Silva, W. R., Frontiera, R. R. Chemical Science, 2018
28. Femtosecond Raman microscopy reveals structural dynamics leading to triplet separation in rubrene singlet fission
Bera, K., Douglas, C. J., Frontiera, R. R. The Journal of Physical Chemistry Letters, 2017
27. Monitoring charge density delocalization upon plasmon excitation with ultrafast surface-enhanced Raman spectroscopy
Keller, E. L., Frontiera, R. R. ACS Photonics, 2017
26. Stimulated Raman Scattering: from bulk to nano
Prince, R. C., Frontiera, R. R., Potma, E. O. Chemical Reviews, 2017
25. Redox Non-innocent Behavior of a Terminal Iridium Hydrazido2-
Pearce, A. J., Cassabaum, A. A., Frontiera, R. R., Tonks, I. A. Angewandte Chemie International Edition, 2016
24. Ultrafast surface-enhanced Raman probing of the role of hot electrons in plasmon-driven chemistry
Brandt, N. C., Keller, E. L., Frontiera, R. R. The Journal of Physical Chemistry Letters, 2016
23. Competition between Reaction and Degradation Pathways in Plasmon-Driven Photochemistry
Brooks, J. L., Frontiera, R. R. The Journal of Physical Chemistry C, 2016
22. Ultrafast and nonlinear surface-enhanced Raman spectroscopy
Gruenke, N. L., Cardinal, M. F., McAnally, M. O., Frontiera, R. R., Schatz, G. C., Van Duyne, R. P. Chemical Physics Reviews, 2016
21. Excited state structural evolution during charge-transfer reactions in Betaine-30
Silva, W. R., Frontiera, R. R. Physical Chemistry Chemical Physics, 2016
20. Towards Label-Free Super-Resolution Microscopy
Silva, W. R., Graefe, C. T., Frontiera, R. R. ACS Photonics, 2016
19. Ultrafast Surface-Enhanced Raman Spectroscopy
Keller, E. L., Brandt, N. C., Cassabaum, A. A., Frontiera, R. R. Analyst, 2015
18. Determination of resonance Raman cross sections for use in biological SERS sensing with femtosecond stimulated Raman spectroscopy
Silva, W. R., Keller, E. L., Frontiera, R. R. Analytical Chemistry, 2014
17. High performance SERS substrates: Advances and challenges
Sharma, B., Cardinal, M. F., Kleinman, S. L., Greeneltch, N. G., Frontiera, R. R., Blaber, M. G., Schatz, G. C., Van Duyne, R. P. MRS Bulletin, 2013
16. Creating, characterizing, and controlling chemistry with SERS hot spots
Kleinman, S., Frontiera, R. R., Henry, A.-I Dieringer, J. A., Van Duyne, R. P., Physical Chemistry Chemical Physics, 2013
15. Fano-like resonances arising from long-lived molecule-plasmon interactions in colloidal nanoantennas
Frontiera, R. R., Gruenke, N. L., and Van Duyne, R. P., Nano Letters, 2012
14. SERS: Materials, applications, and the future
Sharma, B., Frontiera, R. R., Henry, A.-I., Ringe, E., Van Duyne, R. P., Materials Today, 2012
13. Decoding Chemical Reactivity by Femtosecond Stimulated Raman Spectroscopy
Dasgupta, J., Frontiera, R. R., Fang, C., and Mathies, R. A., Encyclopedia of Biophysics, 2012
12. Probing structural evolution along multiple degrees of freedom with femtosecond stimulated Raman spectroscopy
Frontiera, R. R., Fang, C., Dasgupta, J., and Mathies, R. A., Physical Chemistry Chemical Physics, 2012
11. Surface Enhanced-Femtosecond Stimulated Raman Spectroscopy
Frontiera, R. R., Henry, A.-I., Gruenke, N. L., and Van Duyne, R. P., The Journal of Physical Chemistry Letters, 2011
10. Femtosecond Stimulated Raman Spectroscopy
Frontiera, R. R., and Mathies, R. A., Laser and Photonics Reviews, 2011
9. Probing Interfacial Electron Transfer in Coumarin 343 Sensitized TiO2 Nanoparticles with Femtosecond Stimulated Raman
Frontiera, R. R., Dasgupta, J., and Mathies, R. A., Journal of the American Chemical Society, 2009
8. Mapping GFP structure evolution during proton transfer with femtosecond Raman spectroscopy
Fang, C., Frontiera, R. R., Tran, R., and Mathies, R. A., Nature, 2009
7. Ultrafast Excited State Isomerization in Phytochrome Revealed by Femtosecond Stimulated Raman Spectroscopy
Dasgupta, J., Frontiera, R. R., Taylor, K., Lagarias, J. C., and Mathies, R. A., Proceedings of the National Academy of Science, 2009
6. Origin of Negative and Dispersive Features in Resonance Femtosecond Stimulated Raman Spectroscopy
Frontiera, R. R., Shim, S., Mathies, R. A., Ultrafast Phenomena XVI, Springer Series in Chemical Physics, 2009.
5. Origin of Negative and Dispersive Features in Anti-Stokes and Resonance Femtosecond Stimulated Raman Spectroscopy
Frontiera, R. R., Shim, S., Mathies, R. A., Journal of Chemical Physics, 2008
4. Excited-State Structure and Dynamics of cis- and trans-Azobenzene from Resonance Raman Intensity Analysis
Stuart, C. M., Frontiera, R. R., and Mathies, R.A., Journal of Physical Chemistry A, 2007
3. Polarization dependence of vibrational coupling signals in femtosecond stimulated Raman spectroscopy
Frontiera, R. R., Mathies, R. A., Journal of Chemical Physics, 2007
2. Direct observation of anharmonic coupling in the time domain with femtosecond stimulated Raman scattering
Kukura, P., Frontiera, R., Mathies, R. A., Physical Review Letters, 2006
1. Atmospheric mercury speciation in Yellowstone National Park
Hall, B. D., Olson, M. L., Rutter A. P., Frontiera, R. R., Krabbenhoft, D. P., Gross, D. S., Yuen, M., Rudolph, T. M., Schauer, J. J., Science of the Total Environment, 2006